2007, №1

сс. 61-68

Formation of Porosity in Bioresorbable Polymers by their Treatment in Gaseous, Liquid and Supercritical Carbon Dioxide

2007, №1

сс. 61-68

Цитировать

D.Yu. Zalepugin, N.A. Tilkunova, V.S. Mishin, E.N. Glukhan, I.V. Chernyshova, V.L. Korolev

Key words: polymers, porosity, supercritical fluids, carbon dioxide

Methods of processing of bioresorbable polymers (polylactide and polylactide/ polyglycolide copolymers) in gas, liquid and supercritical media are studied. It is shown that processing of such polymers in supercritical medium results in high amounts of carbon dioxide absorbed in a polymer matrix. The following desorption of carbon dioxide leads to the creation of highly developed porosity (up to 2 cm3/g). The treatment of the polymers under study with liquid and gaseous carbon dioxide gives the total pore volume of 0.1 ÷ 0.3 cm3/g.